Origin of sulphate in the unsaturated zone and groundwater of a loess aquifer

The use of the sulphate mass balance (SMB) between precipitation and soil water as a supplementary method to estimate the diffuse recharge rate assumes that the sulphate in soil water originated entirely from atmospheric deposition; however, the origin of sulphate in soil and groundwater is often unclear, especially in loess aquifers. This study analysed the sulphur (δ³⁴S-SO₄) and oxygen (δ¹⁸O-SO₄) isotopes of sulphate in precipitation, water-extractable soil water, and shallow groundwater samples and used these data along with hydrochemical data to determine the sources of sulphate in the thick unsaturated zone and groundwater of a loess aquifer. The results suggest that sulphate in groundwater mainly originated from old precipitation. When precipitation percolates through the unsaturated zone to recharge groundwater, sulphates were rarely dissolved due to the formation of CaCO₃ film on the surface of sulphate minerals. The water-extractable sulphate in the deep unsaturated zone (>10 m) was mainly derived from the dissolution of evaporite minerals and there was no oxidation of sulphide minerals during the extraction of soil water by elutriating soil samples with deionized water. The water-extractable concentration of SO₄ was not representative of the actual SO₄ concentration in mobile soil water. Therefore, the recharge rate cannot be estimated by the SMB method using the water-extractable concentration of SO₄ in the loess areas. This study is important for identifying sulphate sources and clarifying the proper method for estimating the recharge rate in loess aquifers.     

甘肃北山老金厂金矿床载金矿物特征、原位硫同位素组成及其对成矿的指示意义

老金厂金矿床是北山成矿南带最具代表性的中低温岩浆热液型金矿床之一，其规模为中型。依据脉体穿插、矿物共生组合和矿石结构构造等特征，将矿床矿化作用过程划分为石英-黄铁矿阶段（Ⅰ）、石英-含砷黄铁矿-毒砂阶段（Ⅱ）、石英-黄铁矿-多金属硫化物阶段（Ⅲ）和石英-方解石阶段（Ⅳ）。利用电子探针研究了不同成矿阶段载金矿物的元素组成及其分布规律。Ⅰ阶段：黄铁矿以粗粒自形立方体为主，粒度为0.50~1.50 mm，贫As、Au；毒砂含量极少，呈细粒他形。Ⅱ阶段：含砷黄铁矿周围常有大量毒砂产出，含砷黄铁矿多为立方体、五角十二面体，粒度为0.30~1.00 mm，富As、Au；该阶段矿化最为强烈，毒砂主要形成于此时期，多呈棱柱状、柱状、放射状集合体，显示富S亏As特征。Ⅲ阶段：多以黄铁矿-黄铜矿-闪锌矿共生组合脉的形式产出，黄铁矿多呈长条状，以富S、Cu、Zn、Au和贫Fe、As为特征。Ⅳ阶段：矿化作用极弱，毒砂、黄铁矿含量极少，为细粒他形。原位硫同位素组成显示：Ⅰ阶段黄铁矿δ³⁴S_V-CDT值为-3.8‰~-2.9‰，均值为-3.3‰；Ⅱ阶段黄铁矿和毒砂δ³⁴S_V-CDT值为-4.7‰~2.6‰，均值为-3.3‰；Ⅲ阶段黄铁矿和闪锌矿δ³⁴S_V-CDT值主要分布于-1.9‰~1.0‰之间，均值为0.1‰。此3个阶段硫同位素组成反映了成矿期硫主要来源于幔源岩浆，混入了部分地层硫。综合前人研究成果，认为成矿早期至晚期，成矿流体总体上由富S贫As向富As贫S演化。Ⅰ阶段体系处于中性稳定的环境，硫源充足；Ⅱ阶段为贫S富As的高氧逸度环境，由于大气降水对地层的淋滤渗透，混入富As流体，Au可能与As结合形成Au-As络合物，在成矿有利部位富集沉淀；Ⅲ阶段成矿元素种类丰富，体系为富S贫As的弱还原环境，Au很可能与HS^-、S^-形成络合物进入黄铁矿晶格。     

天然裂缝影响下的花岗岩水力裂缝扩展数值模拟

水力压裂技术是成功实现干热岩资源开发利用的重要手段之一，数值模拟技术能够精准预测水力裂缝扩展。针对典型花岗岩，借助黏性单元法，分别模拟了致密花岗岩和天然裂缝存在情况下的水力裂缝扩展特征，得出以下结论：致密花岗岩的水力裂缝形态单一，天然裂缝的存在增加了压裂后裂缝的复杂性；致密花岗岩水力裂缝拓展主要分为憋压和拓展两个交替往复的阶段，当存在天然裂隙时，水力压裂过程会变得复杂；天然裂缝存在时，水力裂缝的缝长和缝宽分别为致密花岗岩的5. 7倍和1. 7倍；缝网的形成需要借助复杂的压裂工艺实现。研究结果可以为增强型地热系统(EGS)储层水力刺激工作提供理论支持。     

倒置显微镜拍照法对浮游植物计数的稳定性分析

准确定量分析湖泊河流中浮游植物群落结构对评价湖泊河流健康和保障人类饮水安全至关重要.显微镜镜检法是定量分析浮游植物群落结构的唯一方法,但不能满足浮游植物计数分析要求.在Utermhl倒置计数管视野法基础上提出倒置显微镜拍照法,使用拍照法对小球藻、四尾栅藻、斜生栅藻3种纯藻样品和鄱阳湖野外样品计数得到:1)在5、10倍物镜下拍照因浮游植物个体太小导致计数不准确,在20、40倍物镜下拍照计数准确,增加拍照次数可较好地避免计数偏差,拍照次数是影响拍照法计数分析的主要因素; 2)小球藻、四尾栅藻、斜生栅藻在20和40倍物镜下分别拍摄5和10张照片时每升浮游植物计数稳定;鄱阳湖野外样品在20和40物镜倍下分别拍摄5、10张照片时每升浮游植物计数稳定; 3)倒置显微镜拍照法比计数框行格法、目镜视野法、目镜行格法和Utermhl倒置计数管视野法计数稳定,变异系数最小为0.812.     

一种基于锚系垂直阵列的水下移动目标警戒方法

提出了一种基于锚系垂直阵列的对水下移动目标警戒的方法，论述了基于锚系垂直阵列时频瞬态特性探测和空间相关性探测的原理。利用海洋环境与目标噪声在时-频域与空间上的差异，对水下移动目标探测警戒，探测概率高且计算相对简便。垂直阵列悬挂于锚系潜标的系留缆或直接作为潜标的系留缆，布放机动灵活、适应水深范围广，可用于对水下移动目标的长周期、定点、大范围实时监测。     

Application of Avaatech X-ray fluorescence core-scanning in Sr/Ca analysis of speleothems

Application of X-ray fluorescence core-scanning(XRF-CS) on both marine and lake sediments has achieved remarkable results. However, its application has not been widely extended to the research on speleothems. In this study, we measure the Sr abundance and the Sr/Ca ratios of three stalagmites(two aragonite stalagmites, one calcite stalagmite) using the state-of-the-art fourth-generation Avaatech high-resolution XRF core scanner. Through comparisons among different scan paths and among different scan resolutions, as well as comparisons with inductively coupled plasma optical emission spectrometer(ICP-OES), Itrax XRF, and Artax XRF results, we confirm that the Avaatech XRF core scanner could precisely, quickly, and nondestructively analyze the high-resolution Sr abundance of speleothems. Furthermore, we combine the stalagmite δ~(18)O records to explore the paleoclimatic significance of the measured stalagmite Sr/Ca.     

湍流度随高度的变化及其对城市宏观地形的依赖

分别构建广州主建成区垂直比例尺为1﹕2 000、1﹕1 000和1﹕500的3个建筑物模型，利用大型边界层风洞，在西北和东南两风向下，基于中性流模拟分析了复杂城市地形下湍流度随高度的变化及其对宏观地形的依赖。结果表明：风廓线指数α与不同高度的湍流度之间的关系密切，利用现有模型，根据4类粗糙度边界层和不同垂直比例尺，可确定相应的湍流度随高度变化模型的主要系数，预测精度高。城市地形下最大湍流度面发育在0~0.2 h之间狭窄的范围内。用湍流度形态指数β来表征湍流度随高度的变化，无论城市屋脊还是平坦地形，随着风程区的延伸，廓线的指数α升高，湍流度形态指数β降低。表明同一高度湍流度值具有由迎风区、丘顶区向背风区增高，沿风程逐渐增大的规律，对地形部位和风程的依赖性强，与来流翻越简单地形时的特征一致。     

浅析广安华蓥山区山水林田湖综合治理措施——以高顶山矿区为例

高顶山矿区位于广安华蓥市城区东南约5km处。长期的采矿活动,导致区内矿山地质环境问题突出,严重影响华蓥山地区人民的生命财产安全。矿山地质环境问题亟待解决。本文通过分析区内主要存在的矿山地质环境问题,提出通过矿山地质灾害、矿山土地恢复、矿山地形地貌景观恢复治理,河道综合整治、道路修复、生态保育、产业提升等措施;消除安全隐患,保障区内人民生命财产安全;改善生态环境,实现华蓥山地区生态环境全面恢复,生态环境质量提升,提高环境承载力,实现区内"山青、水秀、林美、田良"的目标。并对区内的产业转型升级进行了探讨,提出将高顶山矿区建设成具有科普和教育价值的旅游景观目的地;利用矿区独具特色工业人文景观和别致的自然景观,将高顶山矿区建设成集"科普、休闲、康养、户外、探秘"五大功能于一体的矿山公园,推动矿业经济转型升级,促进产业结构转型和经济社会可持续发展。     

The Control of the Spatial and Temporal Differential Evolution of Boundary Faults on Faulted Basins

The boundary faults of faulted basins generally have segmental growth characteristics. Quantitative analysis of fault growth processes and combined models is of great significance for basin formation and evolution and hydrocarbon accumulation. Taking the Fulongquan fault depression in the southern part of the Songliao Basin as an example, using the 3D seismic data and using the fault-displacement length analysis method, the segmental growth and evolution process of the boundary fault is systematically studied, and the control effect of the spatial and temporal differential evolution of boundary faults on faulted basins is analyzed. The study shows that the segmental growth control of the boundary fault of Fulongquan fault depression forms a series of semi-mantle shoals; the sedimentary center of the Shahezi-Yingcheng fault is controlled to migrate from south to north; The slanting and thrusting activities control the height of the anticline trap; the transformation of the boundary fault property controls the evolution of the basin's tectonic pattern from the tandem semi-mantle to the faulted anticline.     

水资源约束下的河西走廊城市经济脆弱性时空演变及其影响因素

城市经济脆弱性作为当前脆弱性研究中的重要领域，为人-地系统耦合研究提供了新的视角，并为城市可持续健康发展提供有益的决策支持和管理方法。依据城市经济脆弱性内涵，基于暴露度、敏感性、适应能力构建了城市经济脆弱性评价指标体系，运用熵权TOPSIS法评价河西走廊地区及区域内五市的城市经济脆弱性，并采用障碍度模型识别影响区域城市经济脆弱性变化的因素。结果显示：（1）2006—2015年，河西走廊地区城市经济脆弱性呈现出先曲折下降（2006—2011年）再波动上升趋势（2012—2015年）；（2）河西走廊地区的城市经济脆弱性具有明显的空间特征，经历了东西高、中部低到整体较高的演变过程；（3）阻碍河西走廊地区城市经济脆弱性降低的障碍因子由适应能力逐步转变为暴露度。针对河西走廊地区各市主要障碍因子，提出针对性优化措施。